Kevin McMahon, August 7, 2004

NOAA Teacher at Sea
Kevin McMahon
Onboard NOAA Ship Ronald H. Brown

July 26 – August 7, 2004

Mission: New England Air Quality Study (NEAQS)
Geographical Area:
Northwest Atlantic Ocean
Date:
August 7, 2004

Weather Data from the Bridge
Lat. 42 deg 33.05 N
Lon. 68 deg 23.03 W
Heading 349 deg
Speed 0 kts
Barometer 1007.91 mb
Rel Humidity 83.96 %
Temp. 16.68 C

Daily Log

0800 hours. The past evening was spent steaming to this point where we are on station. The ship will remain here for all of the morning and part of the afternoon. We will await a fly over by the J31 as well as the NASA DC8. Many of the scientists onboard will also set their equipment with the use of a satellite due to pass overhead in the early afternoon.

My morning was spent helping Dan Wolfe, one of the NOAA meteorologists repair an electrical problem which had disabled the sensors that relay air temperature and relative humidity to computers aboard ship. As you can see from the photos, this was not something you would find in the job description for meteorologists. To solve the problem Dan had to climb up to a crows nest like platform on the masthead near the bow of the ship and then perform a diagnostic test on the electrical circuitry for the systems.

It was finally discovered that a switch box had allowed moisture to enter through leaky gasket. In all, the task it took several hours to complete.

During the time we were engaged with the repair we started to notice a small school of dolphins moving closer to the ship. At first they seemed to keep a distance of about 100 yards but after time, small pods of four or five would move in closer to the ship and investigate our presence in their world. I believe that this type of dolphin is known as the Atlantic White Sided Dolphin. As we were stationary in the water, a flock of shearwaters could be seen loitering off our stern and starboard side. They are a wonderful seabird to watch as they seem to effortlessly propel themselves through the air with a continuous glide, using a ground effect air flow created by an updraft of the sea waves. The dolphins would at times glide under the floating shearwaters and make them alight from the water. They seemed to enjoy this form of teasing as they repeated the act over and over.

During the afternoon I helped Drew Hamilton take more sun readings with his Sunphotometer. As I stated in yesterdays log, the sunphotometer measure the intensity of the suns direct radiation. Because we had a couple of aircraft fly over us today, the J31 and the DC8, and because those platforms contain the same equipment as that aboard the ship, we were able to validate our readings.

Question

Why is it important to have standardized equipment when conducting the same types of experiments by different people in different locations?

Kevin McMahon, August 5, 2004

NOAA Teacher at Sea
Kevin McMahon
Onboard NOAA Ship Ronald H. Brown

July 26 – August 7, 2004

Mission: New England Air Quality Study (NEAQS)
Geographical Area:
Northwest Atlantic Ocean
Date:
August 5, 2004

Weather Data from the Bridge
Lat. 44 deg 03.77 N
Lon. 68 deg 18.53 W
Heading 210 deg
Speed 8.7 kts
Barometer 1005.7 mb
Rel Humidity 79.8%
Temp. 15.4 C

Daily Log

0800 hours. We have left behind the protective cove in the shadow of Mt. Desert Island and are now in the Gulf of Maine of 235 degrees along the Maine coast. The skies ahead look more threatening than the skies we are leaving behind.

1130 hours and we are just off Matinicus Rock Lighthouse. I spent about one hour in the engine room with Keegan Plaskon who is the ships 3rd engineer. A very sophisticated propulsion system not to mention electrical systems, HVAC, and desalinization systems for the ship.

The RONALD H. BROWN is known in the trade as a diesel electric ship. It propulsion system is somewhat unique in that it uses diesel engines to generate electricity which in turn is used to power the motors turning the propellers. On most vessels of this size, there is a direct connection between the diesel engines and the propellers.

The propeller system is also unique in that there is no rudder system to steer by. With the propellers connected to what is known as a thruster, the two aft propellers can be rotated independently of each other a full 360 degrees. When the two aft thrusters are synchronized with the bow thruster and tied in with the ships GPS system, it allows the team of scientist onboard to remain on station in one place for an extended period of time. Wind, tide and currents can be overcome. Last evening we stayed in one position in a small bay near Bass Harbor, ME with the ships bow pointed into the wind. Although the wind was only about 4 knots out of the northeast, the tidal flow was running about seven knots at its peak.

There are three large diesel engines onboard whose primary use is propulsion. Each is a 16 cylinder Caterpillar (Cat 3500). A single Cat can propel the ship along at about 7 knots. As more speed is needed, the other two Cats are brought on line. The top speed of the ship is about 14 knots. But the ship also uses it diesel engines for other needs. There are three other Cats onboard. They are smaller engines with 8 cylinders each. These engines are used to provide the ship with the needed electricity for everyday use, and the BROWN uses a lot of electricity. Besides the need the scientists have for electricity, there scientific equipment runs on 110 AC just like in your TV and refrigerator home. The ship uses its generators to make fresh water, provide climate control, refrigerate its food supplies, and run the sewage treatment system, its navigational system and what seems like an endless list of other needs.

What is the fuel consumption like? I am told that the ship consumes between 5 & 6 thousand gallons of fuel per day.

Question

If there are about 75 scientists and crew aboard, how many gallons are needed per hour per day for each person per day?

The vessel is also capable of producing 4,000 gallons of water per day but that on a normal day the people onboard consume about 3,000 gallons per day for consumption, personal hygiene, toilets and industrial uses.

Question

How many gallons is this per person per hour per day?

Kevin McMahon, August 4, 2004

NOAA Teacher at Sea
Kevin McMahon
Onboard NOAA Ship Ronald H. Brown

July 26 – August 7, 2004

Mission: New England Air Quality Study (NEAQS)
Geographical Area:
Northwest Atlantic Ocean
Date:
August 4, 2004

Weather Data from the Bridge
Lat. 44 deg 07.58 N
Lon. 68 deg 01.74 W
Heading 035 deg
Speed 7.6 kts
Barometer 1005.17 mb
Rel Humidity 98.3%
Temp. 15.5 C

Daily Log

0700 hours and we are off Mount Desert Island. The air is cool with a light fog over the water and partly cloudy skies above.

The morning was spent on a heading of 035 degrees as we continue our move to the Northeast. I am told that we will just make it to the boundary area between the U.S. and Canadian border. Then we will reverse our course. It is hoped that by being close to the coastline and with the winds cooperating that the ships scientist will be able to measure some of the organic biogenics being produces by the forests of Maine. The relationship between the Volatile Organic Compounds (VOC) which are natural in nature, and man made pollutants produced by the combustion of hydrocarbon products is one of the areas that scientist are working to understand.

0930 hours. I have been spending some time on the bridge transferring the Ships Sighting Log to an Excel Spreadsheet File and then putting the file on the ships website so that some of the scientist can compare their pollution data with various ships we have encountered.

I had a brief tour of the LIDAR (Light Radar) operation today. But we needed to cut it short as they were in the middle of a software problem. I plan to return tomorrow when the equipment is functioning more reliably.

1600 hours.

Weather Data from the Bridge
Lat. 44 deg 06.37 N
Lon. 68 deg 12.10 W
Heading 220 deg
Speed 7.4 kts
Barometer 1003.89 mb
Rel Humidity 88.96%
Temp. 15.35 C

We seem to be charting a course to enter one of the many fiords around Mt. Desert Island, ME.

2030 hours. We are in a fjord near Mt. Desert Island off the town of Bass Harbor. Instead of setting the anchor, the ship will hold position with its bow into the wind using its thrusters which are controlled by the GPS system. The plan is for the atmospheric sensors to measure the organic biogenic compounds which are produced by the forests of the surrounding area.

Kevin McMahon, August 3, 2004

NOAA Teacher at Sea
Kevin McMahon
Onboard NOAA Ship Ronald H. Brown

July 26 – August 7, 2004

Mission: New England Air Quality Study (NEAQS)
Geographical Area:
Northwest Atlantic Ocean
Date:
August 3, 2004

Weather Data from the Bridge
Lat. 43 deg 38.65 N
Lon. 69 deg 43.93 W
Heading 096.4 deg
Speed 7.9 kts
Barometer 1009.84 mb
Rel Humidity 99.47%
Temp. 16.5 C

Daily Log

0635 hours and we are in dense pea soup fog.

1120 hours. We have been delayed by the fog but are now underway at a very slow speed, fog horn sounding every minute. The ship need to travel about 10 miles to the entrance to Boothbay harbor so that we can put ashore by launch one of the scientist and bring back to the ship another of the NOAA scientist who has been working at Pease.

I am starting to hear other fog horns in the distance. I spent some time on the bridge. The radar’s give a very accurate view of what’s around us, shoreline as well as vessels large and small in the area, but still it is not perfect and hence the need to proceed slowly.

We made it in very close to the entrance to Boothbay Harbor. I was hoping to get some pictures of the area but we were entirely fogbound. One scientist was sent ashore at approximately 1330 hours but then the return of the launch with the replacement took longer than anticipated. Apparently they became lost in the fog on their return to the ship.

We spent most of afternoon south of the Boothbay area traveling in an east west pattern taking air and water samples. We seem to slide into and out of dense fog…

I spent about an hour today on the bridge. The ability to track and identify an object at sea is so common now that it is taken as a guarantee of safety. The personnel on the bridge made it abundantly clear that it is not.

It is amazing to me that the same technology which is used to see and identify ships at sea is in a way the same technology that allows many of the scientists onboard to identify and measure many different species of chemical compounds.

Question

What size are the smallest particles we can measure in our Chemistry lab at Grady H.S.?

Kevin McMahon, August 1, 2004

NOAA Teacher at Sea
Kevin McMahon
Onboard NOAA Ship Ronald H. Brown

July 26 – August 7, 2004

Mission: New England Air Quality Study (NEAQS)
Geographical Area:
Northwest Atlantic Ocean
Date:
August 1, 2004

Weather Data from the Bridge
Lat. 42 deg 56.49 N
Lon. 70 deg 33.31 W
Heading 235 deg
Speed 8.2 kts
Barometer 1015.4 mb
Rel Humidity 90.2%
Temp. 18.2C

0740 hours. We spent most of the past evening in a stationary position very near the Isle of Shoals. A very beautiful moonlit evening. We now are on a heading almost due east of the Isle of Shoals, again looking for the NYC, Boston plume.

It is a continual quest, not quite like Ahab and his search for the white whale but a quest none the less. The scientists aboard the RONALD H. BROWN have embarked upon a continual search. Someone once said that one of the great joys in life is getting nature to give up one of her secrets. Meaning that the fun and excitement in science is learning how things work. Each in his or her way is really trying to gain an understanding of how the world works.

Today I spoke with Hans Osthoff. He is a young man with an intense desire to learn about the chemistry of our atmosphere. Hans works for NOAA at the Aeronomy Laboratory in Boulder, Colorado. As a young boy he developed a love for chemistry and stayed with it. He now has advanced degrees in Analytical and Physical Chemistry.

Aboard the ship he runs a piece of equipment which is extremely sophisticated. It is called a Cavity Ringdown Spectrometer. It can measure the diffusion of light as it is passed through a sample of air which is contained in a copper tube. At each end of the copper tube there are parabolic mirrors. As a beam of laser light enters the tube, it bounces back and forth many times before exiting at the other end. The time the beam of light spends in the tube is measured and allows scientists to measure concentrations of:

NO2 NO3 N2O5

Once the concentrations have been found, the scientist can then calculate the reactions rates and the products which will be introduced to our atmosphere.

In the end, we will all gain a better understanding of our atmosphere and hopefully learn how to better maintain our environment.

Question

Can you name the three compounds above?

Kevin McMahon, July 31, 2004

NOAA Teacher at Sea
Kevin McMahon
Onboard NOAA Ship Ronald H. Brown

July 26 – August 7, 2004

Mission: New England Air Quality Study (NEAQS)
Geographical Area:
Northwest Atlantic Ocean
Date:
July 31, 2004

Weather Data from the Bridge
Lat. 43 deg 38.20 N
Lon. 69 deg 57.97 W
Speed 8.9 kts
Barometer 1016.68 mb
Rel Humidity 97.27%
Temp. 18.16 C

Daily Log

0835 hours. The wind speed has increased and is now at about 16 kts which lend a slight roll the ship.

We came within a couple of miles of Fletcher Point, ME. Before turning around, at present we are heading in an easterly direction.

Helped to launch an ozonesonde at 1000. The winds had kicked up to about 20 kts out of the southwest which made it somewhat tricky. In all though it was a successful launch.

I learned later that the ozonesonde made it to an altitude of 39.9 kilometers, not the record but pretty close.

I’ve been up on the bridge. The views of the Maine coastline are spectacular.

Talking to some of the men and women who operate the ship I am amazed at the complexity of the vessel. Aside form the scientific aspect, the bridge alone seems to have more in common with a Boeing 747 than it does with a ship on the sea. Gone are the ships wheel and binnacle and the entire nautical flavor as described by Melville.

The RONALD H. BROWN is as modern a ship as you will find on the ocean.

She is 274 feet in length with a beam of 52.5 feet and a draft of 19 feet.

Its diesel engines do not drive the propellers directly, rather they produce electricity which intern powers electric motors that drive the ships twin aft thrusters and single bow thruster. The ship does not have rudders but is instead maneuvered by the thrusters which have the ability to rotate 360 degrees.

The ships wheel has been replaced by a joystick type apparatus which allows for minute movement in all direction. The GPS navigational system allows the ship to maintain a fixed course over an extended period of time or, hold a steady fixed position within one meter of a desired location.

Questions

How does a GPS system work?

Does the GPS system on the ship differ from the one we use for class fieldwork?

Kevin McMahon, July 30, 2004

NOAA Teacher at Sea
Kevin McMahon
Onboard NOAA Ship Ronald H. Brown

July 26 – August 7, 2004

Mission: New England Air Quality Study (NEAQS)
Geographical Area:
Northwest Atlantic Ocean
Date:
July 30, 2004

Weather Data from the Bridge
Lat. 42 deg 37.86 N
Lon. 70 deg 12.37 W
Speed 8.6 kts
Barometer 1018.96 mb
Rel Humidity 93.16%
Temp. 18.9 C

The seas are calm. The skies have a distant haze. The New England atmosphere so common at this time of year. As is usual for the day, at 0700 we sent aloft a radiosonde, and then at 1000 an ozonesonde.

I was lucky enough to see a couple of finback whales; but unfortunately I had left my camera on my bunk, before beginning a discussion with Drew Hamilton about alternative power generation. Many of the scientists lead very diverse lives. Drew has a house in Seattle and wants to get off the electrical grid. He has worked for NOAA for 25 years and has seen much of the world. Thirty years ago he started out at the University of Miami, never in a thousand years dreaming he’d be involved in the kind of research he’s doing.

Ever hear of di-methyl sulfide DMS? As chemistry teacher I’d heard the name but never understood its significance to the atmospheric work the scientist aboard the ship are undertaking. It turns out that di-methyl sulfide is produced by plankton and is part of a planktons waste process. DMS is one of the major contributors of atmospheric sulfur. Overly high levels in the atmosphere can act as a reflective unit not allowing enough sunlight through our atmosphere. As a result, in certain areas the Earth does not receive the needed heat for some of the biological processes to take place.

Weather Data from the Bridge
Lat. 43 deg 17.84 N
Lon. 69 deg 33.83 W
Speed 9.3 kts
Barometer 1018.3 mb
Rel Humidity 86.16%
Temp. 20.65 C

1530 hours and there seems to be a flurry of activity among many of the scientist. A radiosonde is being rapidly readied to be sent aloft. It seems that the ship has reached a position somewhat east of Portland, ME and we have found a plume of ozone. The initial spike on the instrumentation showed 80-85 ppb (parts per billion) but then it jumped again to 101 ppb. This spike in the ozone was enough to request that another ozonesonde be readied and sent aloft. They have also requested a fly over by the DC3 out of Pease. Onboard the DC3 is a LIDAR (Light Radar) which measures atmospheric ozone. I am told that the cost of one ozonesonde is approximately one thousand dollars, so I assume that the readings on the instrumentation are justifying the expense. It will be interesting to see what they all have to say at the evening science meeting which is held each evening at 1930 hours.

We seemed to have found a large plume of ozone. It is as everyone, the science staff at least, had assumed. We have indeed found a large plume of ozone.

1930 hours. We are now heading in a westerly direction for Cape Elizabeth, ME.

Kevin McMahon, July 29, 2004

NOAA Teacher at Sea
Kevin McMahon
Onboard NOAA Ship Ronald H. Brown

July 26 – August 7, 2004

Mission: New England Air Quality Study (NEAQS)
Geographical Area:
Northwest Atlantic Ocean
Date:
July 29, 2004

Weather Data from the Bridge
Lat. 42 deg 43.99
Lon. 70deg 02.99
Barometer 1015.71 mb
Rel Humidity 94.6%
Temp. 17.1 C
Radiosond aloft at 0710.

Daily Log

Science meeting at 0800. It has been decided that we will try to rendezvous with the J31 out of Pease at approximately 1130 and if all goes well send another radiosonde aloft.

Since I came onboard the RONALD H. BROWN on the 26th of July I have been completely amazed at how sophisticated life onboard a modern research vessel has become. On the first day waiting in line for lunch I inquired as to how long we can expect to have the fresh fruits and vegetables? Mr. Whitehead, the chief steward answered me that, “we always serve up fresh salads, very little of our produce is frozen.” When I inquired as to how they do it, I was informed that the ships refrigeration system was equipped with a device which filters out the Ethylene, a compound which causes produce to rot. As a result we can expect to have fresh salads on a daily basis.

This little tidbit of information got me to thinking about the possibility of a lesson plan which would incorporate some chemistry and some biology.

Questions

1. Can you draw the molecular structure of Ethylene?

2. What bacteria are involved in the spoilage of food and how does the elimination of ethylene play a part in this process?

Most of my time over the last 3 days has been spent getting to know the ship, the crew, and the scientific staff. It is odd in that I am being drawn more towards the operation of the vessel than I am to the scientific community. But both aspects are keeping me busy.

I have been working with Dan Wolfe, one of the main meteorologists onboard. I had thought that because I teach Earth Science, I knew something about weather forecasting. I have a long way to go. It has been an education. We have been sending aloft four radiosonde balloons per day. One every six hours. Each device is carried aloft by a balloon filled with helium. The radiosonde sends back to the ship its location, direction of travel, velocity, and altitude as a result of the barometric pressure.

Question

Which gas law equation does one use to calculate the relationship between pressure and volume?

1400 hours and I have just been informed that my hands are needed to assist with the preparation and launch of an ozonesonde. 1500 hours and we have been informed that a DC3 out of Pease will rendezvous with us in about 30 minutes. An ozonesonde has many of the characteristics of the radiosonde but also has the capability to measure ozone levels at various altitudes. It also has a longer life span and stays aloft about 2 hours and 45 minutes. The DC3 is really an aerial platform which has equipment onboard to measure ozone. I have been informed that the DC3 is nearing our location so it is time to fill the balloon.