Amanda Peretich: My First Love (Chemistry and Other Stuff), July 16, 2012

NOAA Teacher at Sea
Amanda Peretich
Aboard Oscar Dyson
June 30, 2012 – July 18 2012

Mission: Pollock Survey
Geographical area of cruise:
Bering Sea
Date:
July 16, 2012

Location Data
Latitude: 58ºN
Longitude: 175ºW
Ship speed: 10.2 knots (11.7 mph)

Weather Data from the Bridge
Air temperature: 8.2ºC (46.8ºF)
Surface water temperature: 6.4ºC (43.5ºF)
Wind speed: 9.9 knots (11.4 mph)
Wind direction: 221ºT
Barometric pressure: 1022.6 millibar (1.01 atm, 767 mmHg)

Chemistry Lab
Chemistry Lab on the Oscar Dyson

Science and Technology Log
Throughout some of my previous posts, I’ve hinted at the amount of science on board the Oscar Dyson. Of course, I got super excited any time I saw something more on the chemistry and physics side of things versus the biology side, mostly because although I love biology, chemistry is definitely my first love. Thus today’s science and technology log will be to share just a few of the gazillion ties to chemistry that I’ve found in the past few weeks.

  1. Cathodic protection system
    Seawater is more corrosive than freshwater and will corrode the steel on the ship, so the Cathelco seawater pipework anti-fouling system on board works to prevent that corrosion from happening. Cathodic protection controls corrosion by making the metal surface the cathode of an electrochemical cell.

    Cathelco
    Cathelco cathodic protection system to prevent ship corrosion.

    Fluorometer
    Fluorometer and TSG on the Oscar Dyson.
  2. Fluorometer
    The fluorometer on the Oscar Dyson is used to measure both chlorophyll and turbidity (cloudiness) of the sea water using fluorescence technology. There is an intake on the keel of the bow that pumps water aft into the chemistry lab where it first goes through a debubbler to remove any excess air and then it goes through the fluorometer and TSG (see next point). Measuring the amount of chlorophyll is a good indication of plant life and thus the amount of phytoplankton and other species in the food chain. This data is also stored on the SCS and available for scientists to use.
  3. Thermosalinograph (TSG)
    Another device that the sea water passes through from the underway system is the TSG. This measures both temperature and conductivity (how much electricity passes through) in the water. There is a fancy mathematical equation that is then used to determine salinity in PSUs, or practical salinity units.
  4. Needle gunning and more
    When we aren’t letting out a net or hauling back in a net, the deck crew work on various things for upkeep around the ship. One day at dinner, they were discussing something called needle gunning. Never having heard of this, I was immediately intrigued, to which Deeno kept telling me “it’s nooooot really that exciting”. Wrong! It’s basically this pneumatic device (something using compressed air) that has a bunch of little rods (needles) in a circular pattern that, when turned on, seems to feel like a jackhammer as the needles press against the surface at quick speeds. They use it on various ship surfaces to clean off rust and corrosion. Following the needle gunning, they can then apply a layer of corroseal rust converter which reacts with any rust (iron oxide) to oxidize and convert it a more stable substance (magnetite) that turns black. After this, they are free to add primer and 2 part paint (different than the paint you’d use at home) to keep things on board looking great and not corroding away.
Needle Gunning
Needle gunning (left) and preparing for painting (right) on the Oscar Dyson.

Personal Log
I’ve been working on my last blog coming up on all of my ship mates since almost the first day on board the Oscar Dyson. Be sure to check it out in a couple days! But before that, I’d like to share some of the fun things I’ve learned or taken note of since we left Dutch Harbor that didn’t really fit nicely anywhere else.

Lingo I’ve Learned

Hawse Pipe
The hawse pipe, through which the anchor is raised and lowered, on the Oscar Dyson.

* hawse pipe: someone who has worked their way up on a vessel, from deck crew to the bridge (1st mate, 2nd mate, executive officer (XO), etc.); this is in reference to the pipe on a ship through which the anchor chain is fed – for example, XO Kris Mackie worked his way up the hawse pipe to get to where he is today
* ringknockers: someone out of NOAA Corps BOT-C (basic officer training class)
* scuttlebutt: rumor or gossip on board; this comes from the idea that a butt (cask) of water that has been scuttled (deliberately “sunk”) so that water could flow, similar to a water fountain, was a place around which people would convene to gossip

Dog All Dogs
Dogging the door.

* dogging the door: handles on various doors on board are fastened to seal it

* leeward: the side of the vessel that is not facing the wind, which changes sides based on wind direction
* windward: the side of the vessel that is facing the wind

Leeward
Kenny reminding you to use the leeward side when opening doors

(wet and dry bulb temperature readings are taken on the bridge hourly on the windward side)
* fantail: another name for the aft deck
* “wagging the tail”: used when the person on the bridge is adjusting various things on the ship to evenly wrap the chains onto the reel when hauling in a trawl
* “alls balls”: refers to midnight, which is 0000 in military time
* head: bathroom/toilet

Weird Facts/Thoughts That Don’t Fit Anywhere Else
– I remember I’m on a male-dominant vessel when the toilet seat in the community head outside the fish lab is always up (there are 3 community heads: one right near the fish lab, one in the gym, and one outside medical – these are used so you don’t have to disturb your roommate while they are sleeping in the room)

– The above fact is okay because the head has the BEST green hand soap in the world with moisturizing beads and a wonderful aroma – sometimes I just go wash my hands in there for the sake of it, which is fine because there are also signs everywhere reminding you to wash your hands

– It doesn’t matter what time of day it is, if I walk into the TV lounge, I will more than likely sit down and watch part of whatever movie is on

– Still in dealing with the TV lounge, the rule on board is that once you start a movie, you have to let it go all the way to the end, because some people on board have TVs in their room hooked up to the movie channels and may be watching it

– There are three movie players: 2 “tape decks” with these 8mm cassette tapes and 1 special DVD player for the NAVY movies and close to 1,000 movies to choose from!

– I’ve watched more movies since I’ve been on board than I probably have watched in the past year combined (although some were parts of movies that I walked in on after they’d started or had to leave early from to fish)

– The internet works via a signal from a geostationary satellite (GE23 at 172 degrees E on the equator) so as we are travel, the receiver on board must look south for signal such that when we are traveling north-northwest, the mast and stack of OD get in the way of the signal and we have no internet

– I could actually make short phone calls using VOIP (voice over IP), but this slows down the internet and you had to limit your calls to 10 minutes or so – it also shows up on the receiving end as a Maryland phone number because that’s where NOAA is located

– My favorite place to just go relax is actually up on the flying bridge – rarely do people go up there (it’s super windy) but when it’s nice outside (also a rarity), it is a beautiful view of nothing but the Bering Sea (and plenty of birds) – just have to make sure to let the officer on deck (OOD) know you’re going up there

Fun with KNOTS
One day, Brian and ENS Kevin attempted to teach me how to tie a bunch of different knots. I have a good idea how my students feel when they don’t understand a concept that seems so easy to me because both guys were just like “you do this this this and this and you’re done” and there I was, back on the first step, completely lost.

I did learn the bowline (which is not pronounced “bow-line” like you’d think, but rather more like “bo-lin”) and the one-handed bowline. Kevin even taught me the dragon bowline, where he tied a bowline knot and dragged it on the floor – get it? 🙂

Knots
Some of the knots I learned to tie on board.

Some other knots I learned: figure 8, square, clove hitch, timber hitch, daisy chain, and becket. Could I repeat those for you today? Possibly, but probably not.

Scavenger Hunt
One of the jobs of the safety officer is to check the Ocenco EEBDs (Emergency Escape Breathing Device) on board to make sure they have not expired. ENS Libby (who just came to the Oscar Dyson on this leg of the pollock survey from NOAA Corps BOT-C) and I went on a scavenger hunt one night to find all of these EEBDs around the ship (aside from the ones inside staterooms). Some of the folks that have been on here for a while laughed a little because I was so excited to go on this little adventure – but it teaches a good lesson: things will only be as exciting as you let them! I also decided to make Libby a scavenger hunt for other random things with clues to the room they were in. She only found one of the three, so no prize for her this time. We also plan to go on a scavenger hunt for fire extinguishers soon!

EEBDs
Hunting for EEBDs (left) with ENS Libby (right).
Cribbage
Good times with cribbage.

Cribbage
Two of the guys in the acoustics lab, Bill and Scott, were constantly playing this card game with a red, white, and blue wooden board that looks sort of like a race track. They would lay out cards, count random numbers, and move these pegs in a fashion that I totally did not understand, no matter how long I sat and watched them. Finally, I stayed up later after my shift one night and Carwyn (my roommate) taught me how to play cribbage (she’d taught the science intern Nate to play the previous night). All of the other scientists are really good at this game, so Nate and I started playing each other as the newbies. We are both getting much better at it (although I ultimately came up with the winning record by the end of the cruise)! One of these days, I hope to be as quick with the counting as Bill and Scott. I even taught Libby how to play last night, although she much prefers rummy, which she then taught me how to play.

Animal Love
Two new animals I’ve seen recently: the crested auklet (this little guy landed on board and stuck around a little over a day near the bow of the ship) and a whole lot of Pacific herring that we caught in the net the other day (which I’ve renamed Vegas fish because they are so sparkly and glittery like Vegas lights).

Crested Auklet
Crested Auklet (Aethia cristatella)
Pacific herring
Pacific herring (Clupea pallasii)

Kathryn Lanouette, July 22, 2009

NOAA Teacher at Sea
Kathryn Lanouette
Onboard NOAA Ship Oscar Dyson
July 21-August 7, 2009 

Mission: Summer Pollock Survey
Geographical area of cruise: Alaska
Date: July 22, 2009

Looking back on Unalaska, AK
Looking back on Unalaska, AK

Weather Data from the Ship’s Bridge 
Visibility: 3 nautical miles
Wind direction: 288.27 degree (N, NW)
Wind speed: 20 knots
Sea wave height: 8-10 feet
Air temperature: 7.4 ˚C
Seawater temperature: 6.8 ˚C
Sea level pressure: 29.3 inches Hg and rising
Cloud cover: 8/ 8, stratus

Science and Technology Log 

It will take about 2 ½ days of non-stop sailing until we reach the fish survey starting area. Before that research gets underway, I’ve been spending a lot of time getting to know my way around the ship and learning about life at sea. My favorite part of the ship to spend time has been the bridge, the navigation and operations base for the entire ship. From the bridge, I’ve been able to learn more about the weather and birds that live at sea. Every hour, the weather is recorded using the boat’s instruments. This weather is then relayed to NOAA’s National Weather Service. Using the Oscar Dyson’s data, the National Weather Service is better able to predict and model weather patterns, increasing their forecast’s accuracy for this remote region. As the waves kicked up a lot on Tuesday evening, I learned about the Beaufort Scale of Wind Force.

Using estimated wave speed and wave height, you can calculate the severity of the weather. On Tuesday evening, we were sailing through a Force 7 on the scale, a gale with wave heights of 13.5 to 19 feet and a wind speed of 28-33 knots (aprox. 35-37 mph) with gusts up to 45 knots (aprox. 50 mph) Luckily, the waves have calmed down a lot by Wednesday evening because the lower pressure system has passed us to the east.

A Northern Fulmar (Courtesy Aaron Lang, USFWS)
A Northern Fulmar (Courtesy Aaron Lang, USFWS)

In addition to fisheries research, there are two bird observers from the U.S. Fish and Wildlife Service (USFWS). For almost 16 hours each day, they observe and record information about the seabirds that they see flying within 300 m of the boat. Seabirds spend most of their lives living out on the open seas, looking for food. A lot is known about their cliff nesting areas by the water because these locations are relatively easier to access. Much less is known about their time spent at sea. The information gathered here helps scientists learn more about the birds that inhabit the Bering Sea. By looking at their data from prior years, they can sea how different birds are affected by human caused events (like oil spills, global warming, and commercial fishing) and non-human caused events like volcanic eruptions. All their research is part a bigger research program called the Bering Sea Integrated Ecosystem Research Program (BSIERP).  As one seabird was flying close to the boat, I noticed it had a slender tube on top of its bill. It turns out that this bird was a Northern Fulmar, part of a group of birds called “tube-noses.” This tube enables the birds to drink saltwater, a cool adaptation to life at sea.

Here I am practicing wearing my immersion suit.
Here I am practicing wearing my immersion suit.

Personal Log 

On Tuesday afternoon, as we left the protected bay of Dutch Harbor, we started sailing out towards the more open waters of the Bering Sea.  It was a strange feeling to see the Fox Islands, a smaller part of the Aleutian Island chain, slipping out of sight. Our next chance of seeing land will be as we get closer to Russia. Even then, it might be too cloudy. It is strange to think that I might not see land again for over two weeks. By 9pm on Tuesday night, I was sick as a dog, “hanging over the rails” if you will. But with some sleep and seasickness medicine, I am feeling a lot better today. Seems I have found my “sea legs” as food seems appealing once more and the boats rocking is becoming more of a lulling motion than a lurching one. Around noon on Wednesday, we had our first fire drill and abandon ship drill. As part of the drills, we had to practice putting on our immersion suits. In case we had to abandon ship for any reason, these suits would keep us warmer and more visible. I felt a bit like Gumby!

Animals Seen 
Northern Fulmar Black Legged Kittiwake Tufted Puffin Horned Puffin Black-Footed Albatross Laysan Albatross Murre

New Vocabulary 
Knots – units of speed, nautical miles per hour Nautical mile – 1.15 statute (regular) mile

Diane Stanitski: Day 18, August 28, 2002

NOAA Teacher at Sea

Diane Stanitski

Aboard NOAA Ship Ka’imimoana

August 16-30, 2002

Day 18: Wednesday, August 28, 2002

The FOO (Field Operations Officer)’s quote of the day: 

“Better three hours too soon than a minute too late.”
– William Shakespeare

Weather Log:
Here are our observations at 0900 today:
Latitude: 3°39.88’S (into the Southern Hemisphere!)
Longitude: 140°00.36’W
Visibility: 12 nautical miles (nm)
Wind direction: 100°
Wind speed: 13 kts
Sea wave height: 4-5′
Swell wave height: 6-8′
Sea water temperature: 27.1°C
Sea level pressure: 1011.7 mb
Cloud cover: 2/8, Cumulus, Cirrus

Hurricane Genevieve lives!

Science and Technology Log:

I stayed up until I couldn’t keep my eyes open anymore last night. I finished the script and lesson plan for today’s broadcast with my graduate students in the Atmospheric Environment class. When I awoke at 0600, I realized that the fish bite test was already in progress on the fantail of the ship. I quickly prepared for my morning broadcast and then went outside to see if I could help place fish heads (mostly red snapper) on the lines that were being tested. The objective of the test was to qualitatively determine the fish-bite protection of a new armored mooring cable. The current cable that is used, nilspin, is very heavy while the cable to be tested is much lighter, but has a greater diameter. The test cable consists of a polyester core wrapped with electrical wires with up to two layers of special cloth armoring with a PE jacket. The cable diameter is ~221 mm. The test consisted of towing three 100 m cables (no armor, single, and double) simultaneously from the stern while the boat moved at 1-2 kts. Fish heads were attached every 3 meters to each cable. I was asked to take notes on the procedure since it was a new experiment and to use a multimeter to ensure that the lines were actually measuring electrical conductivity in case of a fish bite. Occasionally, I managed to assist with the deployment of the lines by helping place mesh bags alongside the line, opening the bag and inserting a partially frozen and slimy head of a fish, attaching the bag to the cable with wire ties, and then placing electrical tape over the wire tie and ends of the bags to keep them attached. It took approximately 2-1/2 hours to prepare the fish lines and deploy them. I really enjoyed it. There’s something exciting about having a group of people working together toward a common goal, especially when science is involved.

We started the broadcast soon after the fish bite test was running and I had the opportunity to interview a number of people on board who hadn’t been highlighted in a past broadcast. They were great! This was a more scientific webcast mostly focused on El Nino and the research conducted on the ship. I loved every minute and learned a great deal in the process. The video is 51 minutes long and can be accessed at on our videos page. Check it out when you have time.

I asked Lobo, our Chief Engineer, how portable water is created on the ship. He provided a great overview of the process. Seawater is converted into fresh water by vacuum distillation. In the end, the water is used for drinking, as process water, and for domestic purposes. The seawater to be distilled evaporates at a temperature of about 40°C (very low temperature for evaporation to occur) as it passes between the hot plates in an evaporator on board. The evaporating temperature corresponds to a vacuum of approximately 93%, which is maintained by the brine/air ejector. The vacuum serves to lower the evaporation temperature of the feed water. Having reach boiling temperature – which is lower than at atmospheric pressure – the feed water undergoes a partial evaporation, and the mixture of generated vapor and brine enters the separator vessel, where the brine is separated from the vapor and extracted by the combined brine/air ejector. The vapors that are generated pass through a demister where any drops of seawater that are entrained are removed and fall to the bottom of the distiller chamber. The vapors continue to the condenser where they condense to fresh water as they pass between cold plates. The freshwater that is produced is extracted by the freshwater pump and led to the freshwater tank. We can store approximately 3000 gallons of water on board.

I conducted a CTD test by myself for the first time tonight at 7:30 PM. Everything worked and we decided to test zucchini, a green pepper, a potato, and a round loaf of bread to see what happens to it when it’s submerged to the extreme pressure at 1000 meters below the water surface. When we finished the CTD cast where we sampled water at 1000m, 800 m, 600 m, 400 m, 200 m, 150, 100 m, 60 m, 40 m, 25 m, 10 m, and the surface, we brought the sampling cylinders up with the food. The potato looked and felt the same, the zucchini was squishy, the green pepper looked exactly the same but it had a crack on the side and was full of water. It must have burst on the way down and filled with water. In this case, the pressure would have been the same from the inside to the outside so no change in size took place. The bread looked like pita bread. It had been placed in plastic wrap, 2 zip-lock bags, and another plastic sleeve, but still managed to get wet. Interesting experiment.

Just after the CTD returned to the surface, I went to the starboard side of the ship to throw in an AOML, a device that measures water currents across the ocean surface (more on this tomorrow). AOMLs float away into the distance but transmit their data on a realtime basis. They are occasionally retrieved, but usually remain in the Pacific forever.

Personal Log:

I am receiving all of your emails – thank you! It’s great to hear that your first week of classes is going well. I will highlight several of your questions in tomorrow’s log!

Congratulations to Steve Osmanski who knew that the term “knot(s)” is a unit of maritime speed goes back to the days of sailing ships, when speed was measured by throwing a wooden device called a “chip log” over the stern of the ship. The chip log had a line attached with knots spaced along it. When the log was thrown overboard, a timing device (usually a 30-second sandglass) was turned and the number of knots that passed through the user’s hand as the line unreeled during the 30 seconds was the ship’s speed in nautical miles per hour. It was reported to the officer of the deck as so many “knots.” The distance between knots in a log line is calculated at 1.688 feet for every second in your timing interval; so a 30-second log line would have knots 50.64 feet (50 feet, 7 and 2/3rds inches, just about). Many of you answered this correctly, but Steve was first!

John and I played Yahtzee tonight in the third round of the match. I managed to win again so I move into the semi-final round.

Question of the day: How long is the Ka’imimoana? Check out Teacher at Sea web site for all the details.

Closer to land, but wishing I was further out to sea…
Diane

Dana Tomlinson: Day 16, March 16, 2002

NOAA Teacher at Sea

Dana Tomlinson

Aboard NOAA Ship Ka’imimoana

March 1 – 27, 2002

Date: Saturday, March 16, 2002
Lat: 8°S
Long: 110°W
Seas: 2-5 ft
Visibility: unrestricted
Weather: partly to mostly cloudy, possibility of rain showers
Sea Surface Temp: 82-86°F
Winds: 5-10 knots
Air Temp: 85-74°F

Today was kind of bittersweet for me but I doubt the crew feels that way. Today, we recovered the buoy at 8°S 110°W and deployed a new one. This will be the last time I have to see the buoy operations, as it is the last recovery/deployment until after the Galapagos Islands – and that’s where I get off. The crew goes on to Manzanillo, Mexico, and then returns to Honolulu, their home base. The operations went perfectly on both ends today, and now the crew gets a chance to catch up on everything they can’t do when they’re doing buoy ops.

We are now in transit from the 110°W line directly east to the 95°W line. We will be in transit for several days. During that time, like I said, the crew will be getting their regular chores done and the scientists will be preparing for the buoy “fly bys” we’ll be doing on the 95°W line. A fly by is when we locate the buoy, the scientists go out to it in the RHIB to check on it, and then fix anything that needs fixing or calibrating with the instrumentation. This transit is a chance for everyone to catch their breath for this next round of operations.

Question of the Day: 

The ship is traveling at about 12 knots. How long will it take us to get from the 110°W to the 95°W? Hint: you’re going to have to find out how many miles it is between degrees of longitude – Internet anyone?

Answer of the Day: 

Once again, Brian R. of San Diego tells me that the Pacific Ocean, on the average, is 13,740 ft deep, or about 4188 meters deep. But does anyone know how deep it is at its deepest point??? Let me hear from you. 🙂

Til tomorrow,
🙂 Dana